Product ID:93512, ECHO 50:1, 25052
MSDS Date:04/17/1989
FSC:9150
NIIN:00N075743
MSDS Number: CCWWZ

CITGO PETROLEUM CORP

TULSA, OK 74102
US

Emergency Phone: 318-491-6215;800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 1JW40

CITIES SERVICE CO

300 TULSA, OK 74102 US

Telephone: 918-561-5165

Cage: 12518

REFINED PETROLEUM OIL(S) (CONSISTING OF ING 2 & 3).

Fraction By Weight: 70-80%

OSHA PEL 5 MG/M3 (OIL MIST)

ACGIH TLV: 5 MG/M3 (OIL MIST)

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED

CAS: 64741-88-4

RTECS: PY8040501

OSHA PEL 5 MG/M3 (MFR)

ACGIH TLV: 5 MG/M3 (MFR)

SOLVENT REFINED RESIDUM

CAS: 64742-01-4

OSHA PEL 5 MG/M3 (MFR)

ACGIH TLV: 5 MG/M3 (MFR)

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 15-25%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

LOW ASH ADDITIVE MIXTURE (CONTAINING ING 6)

Fraction By Weight: 3-8%

OSHA PEL N/K

ACGIH TLV: N/K

PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC

CAS: 68649-42-3

Fraction By Weight: <4%

OSHA PEL N/K

ACGIH TLV: N/K

(ORAL,RAT) 60.3 G/KG.

Fraction By Weight: <1%

OSHA PEL N/K

ACGIH TLV: N/K

RUST PREVENTATIVE SYNERGIST & DE-ICER SURFACTANT (MIXTURE)

Fraction By Weight: <0.5%

OSHA PEL N/K

ACGIH TLV: N/K

RECONDITIONING, RECLAIMING, RECYCLING/DISPOSING OF

RTECS: 9999999ZZ

MANDATED STANDARDS, AS EVALUATED BY DESIGNATED

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SLIGHTLY TO MODERATELY TOXIC. LETHAL
DOSE FOR 150 LB HUMAN ADULT MAY BE 10 TO 250 ML. TEMPORARY
PULMONARY & DERMAL IRRITATION HAZARD. TARGET ORGANS:LUNGS, SKIN
(IRRITANT), CENTRAL NERVOUS SYSTEM (DEPR ESSANT). ING
5:EYE/SKIN:MINOR IRRITANT.ING 7:EYE:SLIGHT IRRITANT. DERMAL:
MODERATE IRRITANT. ING 8:EYE:MAY BE IRRITANT.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF
RESP) . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15
MINUTES, SEEK ASSISTANCE FROM MD . SKIN:FLUSH W/COPIOUS AMOUN TS OF
WATER. CALL MD . INGEST:DO NOT INDUCE VOMITING. CALL MD
IMMEDIATELY.

Flash Point Method:PMCC
Flash Point:135F,57C
Lower Limits:1%
Upper Limits:6%
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING.

Spill Release Procedures:REMOVE SOURCES OF HEAT/IGNIT, PROVIDE ADEQ
VENT, CNTN LEAK. SM SPILL:ABSORB W/SUITABLE MATL SUCH AS RAGS,
STRAW/SAND. LG SPILLS:CNTN SPILL IN EARTHEN DIKES FOR LATER
RECOVERY. RPT SPILLS AS REQD TO AP PROP AUTHS. UNDER SECTION
311(B)(4) OF THE(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE <150F. DO NOT APPLY HIGH
HEAT/FLAME TO CNTNR. KEEP SEPARATE FROM STRONG OXIDIZING AGENTS.
COMBUST LIQ. DO NOT INHALE VAPS NOR PERMIT DERM CONT.
Other Precautions:CNTNS PETRO DISTILS. HARMFUL/FATAL IF SWALLOWED. KEEP
OUT OF REACH OF CHILDREN. PROT MEASURES DURING REPAIR & MAINT OF
CONTAM EQUIP:REFER TO SPECIAL PROT INFO SECTION. AVOID PRLNG CONT
W/OIL. USE POLY MER GLOVES IF EXTENDED, DIRECT (SUPDAT)

Respiratory Protection:NORMALLY NONE REQUIRED. IF HIGH VAPOR OR MIST
CONCENTRATIONS EXPECTED, USE NIOSH APPROVED RESPIRATOR APPROVED FOR
ORGANIC VAPORS & MISTS.
Ventilation:USE IN WELL VENTED AREA. IN CONFINED SPACE, MECH VENT MAY
BE REQD TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW (ING 10)
Protective Gloves:OIL IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR BODY-COVERING WORK CLOTHES TO AVOID PRLNG/RPTD
EXPOSURE.
Work Hygienic Practices:WASH EXPOSED SKIN THOROUGHLY W/SOAP & WATER.
REMOVE & LAUNDER SOILED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
SPILL PROC:CLEAN WATER ACT, DISCHARGES OF CRUDE OIL & PETRO PRODS IN
ANY KIND/FORM TO SURF WATERS MUST BE IMMED REPORTED TO THE
NRC:800-424-8802. OTHER PREC:CONT IS EXPECTED. CAUT:EMPTY CNTNRS
MAY CNT N PROD RESIDUE WHICH COULD INCL FLAMM/EXPLO VAPS. CONSULT
APPROP FED, STATE & LOC AUTHS BEFORE REUSING, (ING 9)

Boiling Pt:B.P. Text:>300F,>149C
Vapor Pres:<20 @ 25C
Vapor Density:>1
Spec Gravity:0.86 (H*2O=1)
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLUE LIQUID; SLIGHT ODOR OF PETROLEUM DISTILLATE.
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CO*2, (CO UNDER INCOMPLETE
COMBUSTION).

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS. IT IS
THE RESPONSIBILITY OF USER TO DETERMINE IF MATL IS HAZ WASTE AT
TIME OF DISP. CHECK BEFORE DISP TO BE SURE YOU ARE IN COMPLIANCE
W/ALL APPLIC LAWS & REGS. CHEMTREC/RCRA EMER HOTLINE
#800-424-9346.

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of Defense. The United States of America in no manner whatsoever,
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disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.